Method for drilling a wellbore with a reduced ferrite sag composition

ABSTRACT

An drilling mud composition is described, which includes an aqueous base fluid, a viscosifier, and a weighting material The drilling mud composition also includes an anti-sagging agent that comprises a dimethylamino methyl ester, such as methyl 5-(dimethylamino)-2-methyl-5-oxopentanoate. The anti-sagging agent may be used to prevent barite sagging, where barite is used as a weighting material. Small amounts of the anti-sagging agent may be used to maintain a low sag factor while drilling, and without causing unwanted increases in viscosity. The anti-sagging agent is effective for both vertical and inclined wellbores.

BACKGROUND OF THE INVENTION Technical Field

The present invention relates to an aqueous-based drilling fluid withlow sag tendency.

Description of the Related Art

The “background” description provided herein is for the purpose ofgenerally presenting the context of the disclosure. Work of thepresently named inventors, to the extent it is described in thisbackground section, as well as aspects of the description which may nototherwise qualify as prior art at the time of filing, are neitherexpressly or impliedly admitted as prior art against the presentinvention.

Drilling fluids play a great role in the success of the drillingoperation. in the practice of drilling and producing formations, rivepersonnel and the environment are exposed to these fluids. Thus, greatefforts must be made when selecting and designing drilling fluids thatare both effective and safe. Drilling fluids are mainly classified intothree categories: water, oil, and gas base.

Drilling fluids are introduced to subterranean formations to fulfillmany functions, mainly to control the formation pressure by applying ahydrostatic pressure on the formation. Therefore, the drilling fluidpressure is normally kept higher than the formation pressure. SeeBourgoyne Jr. A T, Chenevert M E, Millheim, Keith K, Young Jr F S. 1986.Applied Drilling Engineering. Soc Pet Eng 2:514; and Hossain, M E, andAl-Majed, A A. 2015. Fundamentals of Sustainable Drilling Engineering.John Wiley & Sons, each incorporated herein by reference in theirentirety. Consequently, drilling fluid tends to invade the formation andfluid filtrate and solid particles will interact with the formationrocks and fluids. This interaction often causes permanent or temporarydamage to the formation leading to a reduction in well productivity.Thus, fluid loss control additives are added to the drilling fluids tominimize the invasion of fluid filtrate and solid particles and reducethe formation damage. There are many types of fluid loss controladditives used in the oil industry such as polymers, clays, lime,starch, and bridging agents such as calcium carbonate. See Caenn, R,,Harley, H. C. H., Gray, G. R., 2011. Composition and Properties ofDrilling and Completion Fluids, six. ed, Composition and Properties ofDrilling and Completion Fluids. Elsevier, incorporated herein byreference in its entirety.

Another function of drilling fluid is to carry the cuttings from beneaththe drill bit and transport them all the way to the surface whencirculating the drilling fluid. This enables the cuttings to besuspended in the drilling fluid even when the drilling operation stopsand prevents any settlement of solid particles. Furthermore, drillingfluids also help lubricate, cool, and clean the drilling bit throughoutdrilling operations. See Caenn, R., et al., incorporated herein byreference in its entirety.

To properly achieve these functions and to ensure successful and safedrilling operations, drilling fluids should be carefully designed byselecting the appropriate additives to meet the requirements of thedrilled formations and downhole conditions and to maintain the requiredproperties of the drilling fluids. Those properties include density,viscosity, gel strength, filtration, pH, and other rheologicalproperties.

Barite is one of the most common weighting materials used in drillingand completion fluids. Its good properties (high density, lessenvironmental impact, and low production cost) outperform otherweighting materials and make barite a good candidate for drilling oiland gas wells. However, some problems are encountered with bariteweighted drilling and completion fluids, notably: solid invasion, whichcauses formation damage, and permeability reduction near the wellbore.Another major problem usually encountered when drilling withbarite-weighted drilling fluids is solid particle settlement due togravity, which likely causes well control problems. See Mohamed A K,Elkatatny S A, Mahmoud M A, Shawabkeh R A, Al-Majed A A. 2017. TheEvaluation of Micronized Barite as a Weighting Material for CompletingHPHT Wells. Paper SPE-183768-MS presented at the SPE Middle East Oil &Gas Show and Conference. Manama, Kingdom of Bahrain, March 6-9.incorporated herein by reference in its entirety.

Barite sag is a challenging phenomenon encountered while drilling withbarite-weighted fluids, particularly when drilling deep wells, becauseof the critical downhole conditions, i.e. high pressure and temperature,that require high density drilling fluids. Barite sag occurs when bariteparticles separate from the liquid phase and settle down causingvariations in mud density that may result in loss of well control.However, it can occur in both vertical and inclined wells and even instatic or dynamic conditions.

Barite sag, as a type of solids sag, is a complex phenomenon and verylikely to occur in deviated wells, especially in low-shear cases. SeeHanson, P. M., Co, M. D. F., Jr, T. K. T., 1990. Investigation of Barite“Sag” in Weighted Drilling Fluids in Highly Deviated Wells. Paper SPE20423 presented at the 65th Annual Technical Conference and Exhibition.New Orleans. September 23-26, incorporated herein by reference in itsentirety. Although it is very difficult to simulate, a good optimizationand monitoring for mud rheological properties, sound strategies, andtraining for drilling personnel would help manage solids sag andmitigate its consequences. See Scott, P. D., Company, M. O., Zamora, M.,Aldea, C., 2004. Barite-Sag Management: Challenges, Strategies,Opportunities. Paper IADC/SPE 87136 presented at the IADC/SPE DrillingConference, Dallas. March 2-4, incorporated herein by reference in itsentirety.

Many cases of the sag effect were documented in the literature, forinstance, during completing the first well in Hulder - field in theNorth Sea using barite-weighted oil-based mud, a severe kick wasencountered. It occurred because of barite sag, and well geometrycontributed in the sag effect. See Saasen, A., Jordal, O. H., Asa, S.,Burkhead, D., Berg, P. C., Loklingholm, G., Pedersen, E. S., Asa, S.,Turner, J., Harris, M. J., Fluids, C. S., 2002. Drilling HT/HP WellsUsing a Cesium Formate Based Drilling Fluid. Paper IADC/SPE 74541presented at the IADC/SPE Drilling Conference. Dallas. February 26-28,incorporated herein by reference in its entirety. Many research studieswere done to mitigate barite sag in water and oil-based drilling andcompletion fluids.

In 2004, Temple et al. introduced a new method to reduce sag inoil-based and invert emulsion drilling fluid without increasing theviscosity of drilling fluids. Their method comprises adding a lowmolecular weight polyalkyl methacrylate to the drilling fluid withoutadding any copolymer such as vinyl pyrrolidone. See Temple, C.,Paterson, F., Leith, D., 2004. Method for Reducing Sag in Drilling,Completion and Workover Fluids. WO 2004/113467 A1, incorporated hereinby reference in its entirety. Alabdullatif et al. introduced a newformulation of water-based mud to kill over-pressured formations. Theycombined Mn₃O₄ with barite as a weighting material to overcome baritesag tendency that was encountered in previous operations. Mn₃O₄ was veryeffective in enhancing sag performance and minimizing the risk of losingwell control, especially after a long time of static condition. SeeAlabdullatif, Z., Al-yami, A., Wagle, V., Bubshait, A., Al-safran, A.,Aramco, S., 2015. Development of New Kill Fluids with Minimum SaggingProblems for High Pressure Jilh Formation in Saudi Arabia. Saudi AramcoJ. Technol., incorporated herein by reference in its entirety.

In 2017, Mohamed et al. investigated the effect of reducing bariteparticle size, to micronized size, on water-based drilling fluidstability using sag test and zeta potential. They concluded thatreducing barite particle size to micronized size enhances drilling fluidstability, however, it did not eliminate the problem and more effortsare needed to prevent barite sag. See Mohamed A K, et al., incorporatedherein by reference in its entirety Another method to reduce solids sagwas introduced by Davis et al. in 2017. They introduced a new fluidformulation that consists of base fluid (invert emulsion), weightingmaterial (barite), and sag stability enhancer. The sag stabilityenhancer comprises polyethylene glycol (PEG) having a molecular weightof greater than or equal to about 200 g/mol (Davis et al., 2017).

In view of the forgoing, one objective of the present invention is tointroduce a new additive to enhance fluid stability and prevent baritesag in water-based drilling, completion, and workover fluids.

BRIEF SUMMARY OF THE INVENTION

According to a first aspect, the present disclosure relates to adrilling mud composition, which has an aqueous base fluid, aviscosifier, a weighting agent, a fluid loss control additive, and ananti-sagging agent comprising a dimethylamino methyl ester.

In one embodiment, the dimethylamino methyl ester is present at a weightpercentage in a range of 0.10-1.3 wt %, relative to a total weight ofthe drilling mud composition.

In one embodiment, the dimethylamino methyl ester is present at a volumepercentage in a range of 0.25-3.0 wt %, relative to a total volume ofthe aqueous base fluid.

In one embodiment, the dimethylamino methyl ester has a molecular weightin a range of 150-250 g/mol.

In one embodiment, the dimethylamino methyl ester is methyl5-(dimethylamino)-2-methyl-5-oxopentanoate.

In one embodiment, the weighting agent is barite.

In a further embodiment, the barite is in the form of particles having amean diameter in a range of 20-70 μm.

In one embodiment, the anti-sagging agent further comprises LiCl.

In one embodiment, the drilling mud composition has a density in a rangeof 8.34-20 ppg.

In one embodiment, a volume concentration of the dimethylamino methylester is 0.20-3.0 vol % relative to a total volume of the aqueous basefluid.

In one embodiment, the drilling mud composition further comprises afluid loss control additive, a defoamer, a clay stabilizer, a bridgingagent, an antiscalant, a deflocculant, a lubricant, an anionicpolyelectrolyte, and/or a surfactant.

In one embodiment, the drilling mud composition has a sag factor in arange of 0.500-0.520 at a vertical condition at a temperature of180-270° F. and a pressure of 300-800 psi.

In a further embodiment, the sag factor is 90% or less of a sag factorof a substantially similar drilling mud composition that does notcomprise the anti-sagging agent.

In one embodiment, the drilling mud composition has a sag factor in arange of 0.500-0.520 at an inclined condition of 30-60°, at atemperature of 180-270° F., and at a pressure of 300-800 psi.

In a further embodiment, the sag factor is 85% or less of a sag factorof a substantially similar drilling mud composition that does notcomprise the anti-sagging agent.

In one embodiment, the drilling mud composition has a ten-second gelstrength of 14.0 to 20.0 lbf/100 ft², and a ten-minute gel strength of40.0 to 47.0 lbf/100 ft², at a temperature of 60 to 150° F.

In one embodiment, the drilling mud composition has a yield point in arange of 35 to 47 lbf/100 ft², at a temperature of 60 to 150° F.

In one embodiment, the drilling mud composition has a plastic viscosityin a range of 24 to 30 cp, at a temperature of 60 to 150° F.

In one embodiment, the drilling mud composition has a yield point toplastic viscosity ratio in a range of 1.15-1.80 lbf/(1000 ft².cp), at atemperature of 60 to 150° F.

According to a second aspect, the present disclosure relates to a methodof drilling a subterranean geological formation. This involves drillingthe subterranean geological formation to form a wellbore therein. Thedrilling mud composition of the first aspect is injected into thesubterranean geological formation through the wellbore. The anti-saggingagent prevents sagging of the weighting agent in the wellbore.

In a further embodiment, the wellbore is a vertical wellbore, ahorizontal wellbore, a multilateral wellbore, or an extended reachwellbore.

The foregoing paragraphs have been provided by way of generalintroduction, and are not intended to limit the scope of the followingclaims. The described embodiments, together with further advantages,will be best understood by reference to the following detaileddescription taken in conjunction with the accompanying drawings.

BRIEF DESCRIPTION OF THE DRAWINGS

A more complete appreciation of the disclosure and many of the attendantadvantages thereof will be readily obtained as the same becomes betterunderstood by reference to the following detailed description whenconsidered in connection with the accompanying drawings, wherein:

FIG. 1 shows the particle size distribution of the barite sample.

FIG. 2A is the disassembled cell for the sag test.

FIG. 2B is the sag test set up at an inclined condition.

FIG. 3 is a graph showing the effect of additive concentration ondrilling fluid shear stress vs. shear rate (80° F.).

FIG. 4 is a graph showing the effect of additive concentration ondrilling fluid rheological properties (80° F.).

FIG. 5 is a graph showing the effect of additive concentration ondrilling fluid yield point-plastic viscosity ratio (80° F.).

FIG. 6 is a graph showing the effect of additive concentration ondrilling fluid shear stress vs. shear rate (250° F.).

FIG. 7 is a graph showing the effect of additive concentration ondrilling fluid rheological properties (250° F.),

FIG. 8 shows the sag performance of base fluid at vertical (V) andinclined (I) conditions, and at 200° F. and 250° F.

FIG. 9 shows the effect of additive concentration on sag performance ata vertical condition and 250° F.

FIG. 10 shows the effect of additive concentration on sag performance atinclined condition (45° angle) and 250° F.

FIG. 11 shows the effect of additive concentration on filtrationperformance at 250° F.

DETAILED DESCRIPTION OF THE EMBODIMENTS

Embodiments of the present disclosure will now be described more fullyhereinafter with reference to the accompanying drawings, in which some,but not all embodiments of the disclosure are shown.

The present disclosure will be better understood with reference to thefollowing definitions. As used herein, the words “a” and “an” and thelike carry the meaning of “one or more.” Within the description of thisdisclosure, where a numerical limit or range is stated, the endpointsare included unless stated otherwise. It will be further understood thatthe terms “comprises” and/or “comprising,” when used in thisspecification, specify the presence of stated features, integers, steps,operations, elements, and/or components, but do not preclude thepresence or addition of one or more other features, integers, steps,operations, elements, components, and/or groups thereof.

As used herein, the words “about,” “approximately,” or “substantiallysimilar” may be used when describing magnitude and/or position toindicate that the value anchor position described is within a reasonableexpected range of values and/or positions. For example, a numeric valuemay have a value that is +/−0.1% of the stated value (or range ofvalues), +/−1% of the stated value (or range of values), +/−2% of thestated value (or range of values), +/−5% of the stated value (or rangeof values), +/−10% of the stated value (or range of values), +/−15% ofthe stated value (or range of values), or +/−20% of the stated value (orrange of values) Within the description of this disclosure, where anumerical limit or range is stated, the endpoints are included unlessstated otherwise. Also, all values and subranges within a numericallimit or range are specifically included as if explicitly written out.

As used herein, “compound” is intended to refer to a chemical entity,whether as a solid, is liquid, or gas, and whether in a crude mixture orisolated and purified.

As used herein, “composite” refers to a combination of two or moredistinct constituent materials into one. The individual components, onan atomic level, remain separate and distinct within the finishedstructure. The materials may have different physical or chemicalproperties, that when combined, produce a material with characteristicsdifferent from the original components. In some embodiments, a compositemay have at least two constituent materials that comprise the sameempirical formula but are distinguished by different densities, crystalphases, or a lack of a crystal phase (i.e. an amorphous phase).

The present disclosure is intended to include all hydration states of agiven compound or formula, unless otherwise noted or when heating amaterial. For example, Ni(NO₃)₂ includes anhydrous Ni(NO₃)₂,Ni(NO₃)₂·6H₂O, and any other hydrated forms or mixtures. CuCl₂ includesboth anhydrous CuCl₂ and CuCl₂·2H₂O.

In addition, the present disclosure is intended to include all isotopesof atoms occurring in the present compounds and complexes. Isotopesinclude those atoms having the same atomic number but different massnumbers. By way of general example, and without limitation, isotopes ofhydrogen include deuterium and tritium. Isotopes of carbon include ¹³Cand ¹⁴C. Isotopes of nitrogen include ¹⁴N and ¹⁵N. Isotopes of oxygeninclude ¹⁶O, ¹⁷O, and ¹⁸O. Isotopes of nickel include ⁵⁸Ni, ⁶⁰Ni, ⁶¹Ni,⁶²Ni, and ⁶⁴Ni. Isotopically-labeled compounds of the disclosure maygenerally be prepared by conventional techniques known to those skilledin the art or by processes analogous to those described herein, using anappropriate isotopically-labeled reagent in place of the non-labeledreagent otherwise employed.

As defined here, a drilling mud composition, or “drilling mud,” or“drilling fluid,” is a specially designed fluid that is circulated in awellbore or borehole as the wellbore is being drilled in a subterraneanformation to facilitate the drilling operation. As used herein, the term“drilling operation” shall mean drilling, running casing, and/orcementing unless indicated otherwise. The various functions of adrilling fluid include removing drill cuttings from the wellbore,cooling and lubricating the drill bit, aiding in support of the drillpipe and drill bit, and providing a hydrostatic head to maintain theintegrity of the wellbore walls and prevent well blowouts. Specificdrilling fluid systems are selected to optimize a drilling operation inaccordance with the characteristics of a particular geologicalformation.

As used herein, a “wellbore” includes any geological structure orformation, that may contain various combinations of natural gas (i.e.,primarily methane), light hydrocarbon, or non-hydrocarbon gases(including condensable and non-condensable gases), light hydrocarbonliquids, heavy hydrocarbon liquids, crude oil, rock, oil shale, bitumen,oil sands, tar, coal, and/or water. Exemplary non-condensable gasesinclude hydrogen, helium, carbon monoxide, carbon dioxide, methane, andother light hydrocarbons.

According to a first aspect, the present disclosure relates to adrilling mud composition, comprising an anti-sagging agent. Theanti-sagging agent comprises or consists of a dimethylamino methylester, and the anti-sagging agent may also be called a sag stabilityenhancer. The dimethylamino methyl ester may be present at a weightpercentage in a range of 0.10-0.50 wt %, or 0.10-1.3 wt %, preferably015-1.2 wt %, more preferably 0.20-1.0 wt %, even more preferably0.25-0.9 wt %, or 0.25-0.8 wt % relative to a total weight of thedrilling mud composition. In alternative embodiments, the dimethylaminomethyl ester may be present at a weight percentage greater than 1.3 wt%, for instance, 1.4-1.7 wt %, relative to a total weight of thedrilling mud composition.

In one embodiment, the dimethylamino methyl ester is present at a volumepercentage in a range of 0.20-3.0 vol %, 0.25-3.0 vol %, preferably0.3-1.5 vol %, 0.4-1.2 vol % or 0.5-1.0 vol %, more preferably 0.6-0.9vol %, even more preferably 0.65-0.85 vol %, relative to a total volumeof the aqueous base fluid. In alternative embodiments, the dimethylaminomethyl ester may be present at a volume percentage greater than 3.0 vol%, for instance, 3.2-3.5 vol %, 3.3-3.6 vol %, or 3.4-4.0 vol %. In oneembodiment, the concentration range of 0.25-3.0 vol % relative to atotal volume of the aqueous base fluid may be considered equivalent orsimilar to the concentration range of 0.1-1.3 wt % relative to a totalweight of the drilling mud composition.

In one embodiment, the dimethylamino methyl ester has a molecular weightin a range of 100-350 g/ enol, preferably 150-250 g/mol, more preferably160-240 g/mol, even more preferably 165-200 g/mol. In one embodiment,the dimethylamino methyl ester would not be considered a polymer. In apreferred embodiment, the dimethylamino methyl ester is methyl5-(dimethylamino)-2-methyl-5-oxopentanoate, and may also go by the name“pentanoic acid, 5-(dimethylamino)-2-methyl-5-oxo-, methyl ester,” or bythe trade name RHODIASOLV POLARCLEAN. In an alternative, some othermodified urea may be used as the dimethylamino methyl ester.

In one embodiment, the dimethylamino methyl ester may be present in theanti-sagging agent at a weight percentage of 40-70 wt %, preferably50-65 wt %, more preferably 55-62 wt % relative to a total weight of theanti-sagging agent. The anti-sagging agent may also comprise LiCl at aweight percentage of 0.5-4.0 wt %, preferably 0.7-3.0 wt % relative to atotal weight of the anti-sagging agent. The remaining weight percentageof the anti-sagging agent may come from water or an aqueous base fluid.The anti-sagging agent may have a dynamic viscosity in a range of500-900 mPa·s, preferably 600-850 mPa·s, more preferably 650-800 mPa·s,or about 770 mPa·s. The anti-sagging agent may have a density in a rangeof 1.02-1.18 g/cm², preferably 1.08-1.14 g/cm², or about 1.11 g/cm².

In one embodiment, the drilling mud composition also comprises anaqueous base fluid, a weighting agent and a viscosifier. In someembodiments, the drilling mud composition further comprises a fluid-losscontrol additive. The aqueous base fluid may refer to anywater-containing solution, including saltwater, hard water, and/or freshwater. For purposes of this description, the term “saltwater” willinclude saltwater with a chloride ion content of between about 6000 ppmand saturation, and is intended to encompass seawater and other types ofsaltwater including groundwater comprising additional impuritiestypically found therein. The term “hard water” will include water havingmineral concentrations between about 2000 mg/L and about 300,000 mg/L.The term “fresh water” includes water sources that comprise less than6000 ppm, preferably less than 5000 ppm, preferably less than 4000 ppm,preferably less than 3000 ppm, preferably less than 2000 ppm, preferablyless than 1000 ppm, preferably less than 500 ppm of salts, minerals, orany other dissolved solids. Salts that may be present in saltwater, hardwater, and/or fresh water may be, but are not limited to, cations suchas sodium, magnesium, calcium potassium, ammonium, and iron, and anionssuch as chloride, bicarbonate, carbonate, sulfate, sulfite, phosphate,iodide, nitrate, acetate, citrate, fluoride, and nitrite. The aqueousbase fluids are ordinarily classified as saltwater fluids when theycontain over 1% salt (about 6000 ppm of chloride ion). As used herein,the term “high density brine” refers to a brine that has a density ofabout 9.5-10 ppg (pounds per gallon) or greater, which is equivalent to1.1 g/cm³-1.2 g/cm³ or greater. In one embodiment, the aqueous basefluid is present in the drilling mud composition at a weight percentageof 30-80 wt %, preferably 32-70 wt %, more preferably 35-60 wt %, evenmore preferably 36-50 wt %, or about 38 wt %, relative to a total weightof the drilling mud composition. In one embodiment, the drilling mudcomposition may be considered an aqueous-based drilling fluid.

Weighting agents are commonly used to the density of drilling fluids.Barite or barytes (barium sulphate) is a typical weighting agent,although other minerals may be used. Preferably the drilling mudcomposition comprises a weighting agent, and the weighting agent may bepresent to produce a desired bulk density in the drilling mudcomposition. In preferred embodiments, the weighting agent comprisesbarite particles. Weighting agents other than barite can be used in anyof the embodiments described herein. Other weighting agents includeminerals such as hematite, magnetite, iron oxides, illmenite, siderite,celestite, dolomite, olivine, calcite, magnesium oxides, halites,calcium carbonate, strontium sulfate, manganese tetraoxide and the like.Other weighting agents can also be envisioned by those of ordinary skillin the art.

The weighting agent may be in the form of particles having a meandiameter or longest dimension in a range of 20-70 μm, preferably 30-60μm, more preferably 32-50 μm, even more preferably 35-42 μm. However, insome embodiments, the particles may have an average mean diameter ofless than 20 μm. In a preferred embodiment, the weighting agent isbarite in the form of particles having a diameter of 20-70 μm. Theweighting agent may be present in the drilling mud composition at aweight percentage of 30 60 wt %, preferably 35-58 wt %, more preferably40-57 wt %, or about 55 wt %, relative to a total weight of the drillingmud composition. In one embodiment, the drilling mud composition may beconsidered a barite-weighted drilling fluid. Further, the drilling mudcomposition may be considered a barite-weighted aqueous-based drillingfluid.

In one embodiment, barite may be added to form the drilling mudcomposition from a source that may also comprise impurities, such assodium sulfate, aluminum oxide, manganese tetraoxide, potassium formate,hematite, siderite, ilmenite, cement, pyrrhotite, gypsum, anhydrite,calcium carbonate, and the like, in a preferred embodiment, an amount ofbarite in the barite source is at least 80 wt %, preferably at least 90wt %, preferably at least 95 wt %, preferably at least 99 wt %, relativeto a total weight of the barite source. In one embodiment a, baritesource may be contacted with a leaching acid prior to forming thedrilling mud composition, in order to leach and remove acid-solubleimpurities from the pure barite. In one embodiment, the leaching acid isa mineral acid selected from the group consisting of hydrochloric acidand/or sulfuric acid.

As mentioned previously, the drilling mud composition may comprise aviscosifier. In one embodiment, one or more viscosifiers are present inthe drilling mud composition at a combined weight percentage of 0.1-2.0wt %, preferably 0.5-1.5 wt %, more preferably 0.7-1.0 wt %, or about0.86 wt %, relative to a total weight of the drilling mud composition.Exemplary viscosifiers include, but are not limited to bauxite,bentonite, dolomite, limestone, calcite, vaterite, aragonite, magnesite,taconite, gypsum, quartz, marble, hematite, hectorite, bentonite,limonite, magnetite, andesite, garnet, basalt, dacite, nesosilicates ororthosilicates, sorosilicates, cyclosilicates, inosilicates,phyllosilicates, tectosilicates, kaolins, montmorillonite, fullersearth, halloy site, xanthan gum (XC-polymer), xanthan gum, guar gum,glycol, carboxymethylcellulose, polyanionic cellulose, and the like.Viscosifiers may also be called “thickeners,” and are used to increasethe viscosity of the drilling mud composition.

In a preferred embodiment, the viscosifier comprises bentonite.Bentonite is an absorbent aluminum phyllosilicate, an impure clayconsisting primarily of montmorillonite. Montmorillonite generallycomprises sodium, calcium, aluminum, magnesium, and silicon, and oxidesand hydrates thereof. Other compounds may also be present in thebentonite of the present disclosure, including, but not limited to,potassium-containing compounds, and iron-containing compounds. There aredifferent types of bentonite, named for the respective dominant element,such as potassium (K), sodium Na), calcium (Ca) and aluminum (Al).Therefore, in terms of the present disclosure “bentonite” may refer topotassium bentonite, sodium bentonite, calcium bentonite, aluminumbentonite, and mixtures thereof, depending on the relative amounts ofpotassium, sodium, calcium, and aluminum in the bentonite.

In a preferred embodiment, the drilling mud composition comprises bothXC-polymer and bentonite as viscosifiers. Xanthan gum (XC-polymer) is apolysaccharide and biopolymer, and derives its name from the species ofbacteria used during the fermentation process, Xanthomonas campestris.The addition of XC-polymer may cause the viscosity of the drilling mudcomposition to decrease with higher shear rates, which behavior iscalled shear thinning or pseudoplasticity. The XC-polymer and thebentonite may be present with a XC-polymer to bentonite mass ratio in arange of 1:10-10:1, preferably 1:3-1:1, more preferably 1:2-1:4, orabout 1:2.7.

In one embodiment, the drilling mud composition comprises one or morefluid loss control additives. Fluid loss control additives limit theloss of drilling fluids into permeable formations. In other words, fluidloss control additives limit the amount of filtrate that permeates intoa permeable formation. Fluid loss control additives may also be called“fluid loss additives,” or “filtration control additives.” These includebut are not limited to, starch, guar gum, carboxymethyl cellulose,crospovidone, croscarmellose sodium, sodium starch glycolatepolysaccharides, polyanionic cellulose polymer, and acrylic polymerssuch as polyacrylamide, or a clay deflocculant. Starch includes but isnot limited to corn starch, tapioca starch, potato starch. In oneembodiment, the fluid loss control additive, or a combined weight of theone or more fluid loss control additives, may be present at a weightpercentage of 0.80-1.5 wt %, preferably 1.0-1.2 wt %, or about 1.1 wt %relative to a total weight of the drilling mud composition. In oneembodiment, the drilling mud composition may comprise both polyanioniccellulose polymer and starch as fluid loss control additives. The starchmay be any commercially available starch used in the field of petroleumextraction, or may be some other type of starch. The polyanioniccellulose polymer may go by the trade name PAC-R. A mass ratio of thestarch to the polyanionic cellulose polymer may be in a range of1:10-10:1, preferably 2:1-8:1, more preferably 3:1-7:1, or about 5.8:1.

In some embodiments, certain additives may have more than one function,or may be grouped with one or more additives. For instance, XC-polymermay be considered both a is viscosifier and a fluid loss controladditive.

In one embodiment, the drilling mud composition may comprise a defoamerat a weight percentage of 0.001-0.1 wt %, preferably 0.005-0.05 wt %,more preferably about 0.01 wt %, relative to a total weight of thedrilling mud composition. A defoamer helps gas escape from the drillingmud composition. Defoamers include, but are not limited to, glycol,silicone, sulfonated hydrocarbons, octanol, and aluminum stearate. Adefoamer may also be called an anti-foam agent or a foam breaker. In oneembodiment, the defoamer may be D-AIR 3000, D-AIR 3000L, D-AIR 4000L,NF-1, NF-3, NF-7, D-AIR 2, and/or D-AIR 1, available from Halliburton,or some other defoamer.

In one embodiment, the drilling mud composition may comprise sodiumcarbonate (also known as “soda ash”) at a weight percentage of 0.01-0.5wt %, preferably 0.05-0.15 wt %, or about 0.08 wt %. The soda ash may beused to maintain calcium levels, and in alternative embodiments, othercompounds may be added with or in place of the soda ash for the samepurpose.

In one embodiment, the drilling mud composition may comprise a metalhydroxide at a weight percentage of 0.01-0.5 wt %, preferably 0.05-0.15wt %, or about 0.08 wt %. The metal hydroxide may be NaOH, KOH, LiOH,Ca(OH)₂, or some other metal hydroxide. Preferably the metal hydroxideis KOH, and may be added for pH adjustment to achieve a final pH in arange of 8.5-11.5, preferably 9.0-11.0, more preferably 9.2-10.8.

In one embodiment, the drilling mud composition may comprise a claystabilizer at a weight percentage of 1-5 wt %, preferably 2-4 wt %, orabout 3 wt %, relative to a total weight of the drilling mudcomposition. The clay stabilizer may be a halide salt such as NaCl, NaI,NaBr, KCl, Kl, KBr, or some other halide salt. Preferably the claystabilizer is KCl.

In one embodiment, the drilling mud composition may comprise a bridgingagent or bridging material at a weight percentage of 0.1-1.5 wt %,preferably 0.2-1.3 wt %, more preferably 0.6-1.2 wt %, or about 0.8 wt%, relative to a total weight of the drilling mud composition. The roleof the bridging agent may be to insert into the pore openings of aformation. The bridging agent may lead to the formation of a filtercake, which prevents loss of drilling fluid. The bridging agent may becalcium carbonate, other suspended salts, or resins. Preferably thebridging agent is calcium carbonate (CaCO₃).

In a preferred embodiment, the drilling mud composition comprises wateror an aqueous base fluid at a weight percentage of 35-60 wt %, or about38.5 wt %, a defoamer at about 0.01 wt %, soda ash at about 0.08 wt %,XC-polymer at 0.23-0.25 wt %, bentonite at 0.2-1.0 wt %, or about 0.6 wt%, KOH at about 0.08 wt %, starch at 0.5-1.5 wt % or about 0.9 wt %,poly anionic cellulose polymer at 0.1-0.2 wt % or about 0.15 wt %, KClat 3-4 wt %, or about 3.15 wt %, CaCO₃ at 0.5-1.0 wt %, or about 0.8 wt%, barite (or a barite source) at 30-60 wt %, or about 55 wt %, and theanti-sagging agent at 0.1-1.2, or about 0.6 wt %, each relative to atotal weight of the drilling mud composition. In one embodiment, thedrilling mud composition consists of water, a defoamer, soda ash,XC-polymer, bentonite, KOH, starch, polyanionic cellulose polymer, KCl,CaCO₃, barite, and anti-sagging agent at the weight percentages aspreviously listed, and the anti-sagging agent consists of water, LiCl,and a dimethylamino methyl ester. In another related embodiment, thedrilling mud composition consists of water, a defoamer, soda ash,XC-polymer, bentonite, KOH, starch, polyanionic cellulose polymer, KCl,CaCO₃, barite (or a barite source), and anti-sagging agent at thepreviously listed weight percentages, but here, the anti-sagging agentconsists of the dimethylamino methyl ester.

In an alternative embodiment, the drilling mud composition may comprisea surfactant at a weight percentage of 0.1-5.0 wt %, preferably 0.2-1.0wt %, relative to a total weight of the drilling mud composition. Thesurfactant may be considered an interfacial tension reducer, though itmay also be present to assist with stabilization of an emulsion. Withoutlimitation, illustrative surfactants suitable for use in the drillingmud composition include acid hydrolyzable mixed alkyldiethanol amides,alkyl glucosides, polyalkylglucosides, alkylalkoxypolydimethylsiloxanes,polyakldimethylsiloxanes, fatty acids, soaps of fatty acids, amidoamines, polyamides, polyamines, oleate esters, imidazoline derivatives,oxidized crude tall oil, organic phosphate esters, alkyl aromaticsulfates, alkyl aromatic sulfonates, alkyl sulfates, alkyl sulfonates,monoesters of polyalkoxylated sorbitan, polyester polyols, aliphaticalcohol esters, aromatic alcohol esters, ammonium salts of polyacrylicacid, and ammonium salts of 2-acrylamido-2-methylpropane sulfonicacid/acrylic acid copolymer.

In an alternative embodiment, the drilling mud composition may comprisean antiscalant at a weight percentage of 0.1-5.0 wt %, preferably0.2-1.0 wt %, relative to a total weight of the drilling mudcomposition. The term “antiscalant” refers to any chemical agent thatprevents, slows, minimizes, and/or stops the precipitation of scale(e.g. calcium carbonate, calcium sulfate, barium sulfate, strontiumsulfate, calcium phosphate, calcium fluoride, calcium silicate,magnesium hydroxide, zinc carbonate, and the like) from the aqueous saltsolution. Antiscalants which may be used in the present disclosureinclude, phosphine or sodium hexametaphosphate, sodium tripolyphosphateand other inorganic polyphosphates, hydroxy ethylidene diphosphonicacid, butane-tricarboxylic acid, phosphonates, or phosphoric acids suchas amino tris (methylenephosphonic acid) (ATMP), etc. carboxylgroup-containing starting material acids, maleic acid, acrylic acid anditaconic acid and the like, polycarboxylic acid polymers, sulfonatedpolymers, vinyl sulfonic acid, allyl sulfonic acid, and3-allyloxy-2-hydroxy-propionic acid and other vinyl monomers having asulfonic acid group, or a non-ionic acrylamide monomer from the vinylcopolymer, and the like. Further, organic acids which are safe under theFDA GRAS guidelines for food production yet still effective indecomposition of carbonates found in the soils and in rock formationsmay be used. The basic principle action of organic acids on carbonatesis to cause the disassociation or the carbonate to produce the oxide andcarbon dioxide. The first group of suitable organic acids is lactic,acetic, formic, fumaric, citric, oxalic, adipic and uric. The secondgroup of suitable organic acids is the carboxylic acids, whose acidityis associated with their carboxyl group —COOH. Sulfonic acids,containing the group —SO₂OH, are relatively stronger acids. The relativestability of the conjugate base of the acid determines its acidity. Insome biological systems more complex organic acids such as L-lactic,citric, and D-glucuronic acids are formed. These use the hydroxyl orcarboxyl group. The third group of suitable organic acids is humic,sebacic, stearic, gallic, palmitic, caffeic, glyoxylic, fulvic,carnosic, anthranilic, ellagic, lipoic, chlorogenic, rosmarinic,phosphoric, methacrylic, oleanic, nitrohumic, florocinnamic,hexaflorosilicic, hydrofluoric, hydroxycitric and silicofluoric. Thefourth group of suitable organic acids includes acetic, malic, citric,tartaric, oxalic, boric, and tnandelic acid. The fifth group of suitableorganic acids includes beta hydroxy acids which are a type of phenolicacid. Salicylic acid is a colorless crystalline organic acid, whose mainactive ingredient is obtained from this source, is a monohydroxybenzoicacid.

In an alternative embodiment, the drilling mud composition may comprisea deflocculant at a weight percentage of 0.1-5.0 wt %, preferably0.2-1.0 wt %, relative to a total weight of the drilling mudcomposition. A deflocculant is a chemical additive to prevent a colloidfrom coming out of suspension or to thin suspensions or slurries, andmay be used to reduce viscosity of clay-based fluids. One type ofdeflocculant is an anionic polyelectrolyte, such as acrylates,polyphosphates, lignosuifonates (Lig), or tannic acid derivates such asquebracho.

In one embodiment, the drilling fluid composition also includes alubricant, at a weight percentage of 0.1-5.0 wt %, preferably 0.2-1.0 wt%, relative to a total weight of the drilling mud composition, forlubrication and further fluid loss control. The lubricant may be asynthetic oil or a biolubricant, such as those derived from plants andanimals, for example, vegetable oils. Synthetic oils include, but arenot limited to, polyalpha-olefin (PAO), synthetic esters, polyakleneglycols (PAG), phosphate esters, alkylated naphthalenes (AN), silicateesters, ionic fluids, multiply alkylated cyclopentanes (MAC). Exemplaryvegetable oil-based lubricants (i.e. biolubricants) that may be used inthe present disclosure include canola oil, castor oil, palm oil,sunflower seed oil, and rapeseed oil from vegetable sources, and talloil from tree sources, and the like.

A drilling fluid of this disclosure may optionally comprise any numberof additional additives. Examples of such additional additives include,without limitation, gelling agents, corrosion inhibitors, rheologycontrol modifiers or thinners, temporary viscosifying agents, hightemperature/high pressure control additives, emulsification additives,acids, alkalinity agents, pH buffers, fluorides, gases, nitrogen, carbondioxide, surface modifying agents, tackifying agents, foamers,catalysts, clay control agents, biocides, bactericides, frictionreducers, antifoam agents, dispersants, flocculants, H₂S scavengers, CO₂scavengers, oxygen scavengers, friction reducers, breakers, relativepermeability modifiers, resins, particulate materials (e.g., proppantparticulates), welling agents, coating enhancement agents, filter cakeremoval agents, odorants, shale stabilizers, oils, and the like. One ormore of these additives may comprise degradable materials that arecapable of undergoing irreversible degradation downhole. A personskilled in the art, with the benefit of this disclosure, will recognizethe types of additives that may be included in the drilling mudcomposition for a particular application, without undue experimentation.

In one embodiment, the drilling mud composition has a density in a rangeof 8.34-20 ppg, preferably 9-18 ppg, more preferably 10-17 ppg, evenmore preferably 13-16 ppg, or about 15 ppg. This density may be obtainedat a temperature in a range of 60-300° F., preferably 80-200° F.

Generally, increased viscosity leads to improved suspension of weightingagents which in turn limits or reduces problematic “sag.” However,excessive viscosity can have adverse effects on equivalent circulatingdensity (causing it to increase), which can also lead to problems,particularly in wells where the differences in subterranean formationpore pressures and fracture gradients are small, as commonly encounteredin deep water wells.

Under certain well conditions, including without limitation, wellgeometries, temperatures, and pressures, a phenomenon called “baritesag” or “sag” can occur. “Sag” is generally a significant variation inmud density (>0.5 lbm/gal) along the mud column, which is the result ofsettling of the weighting agent or weight material and other solids inthe drilling fluid. Sag generally results from the inability of thedrilling fluid under the particular well conditions to provide adequatesuspension properties. Sag may result in formation of a bed of theweighting agents on the low side of the wellbore, and stuck pipe, amongother things. In some cases, sag may be deleterious to a drillingoperation and lead to hole abandonment.

As described herein, the “sag factor” is the ratio of the bottom densityto the sum of the top and bottom densities, each of the same volume ofdrilling mud composition and following a certain time period of aging.“Sag” generally refers to the tendency of a weighting agent to migrateor settle to the bottom, causing an increase in the sag factor.Suspensions of solids in non-vertical columns are known to settle fasterthan suspensions in vertical ones. This effect is driven by gravity andimpeded by fluid rheology, particularly non-Newtonian and time dependenttheology.

A sag factor of exactly 0.5 refers to no difference in top and bottomdensities (for both vertical and non-vertical columns), and thus no sagtendency. Some amount of sag is considered acceptable, for instance,drilling fluids that show a sag factor in a range of 0.50-0.53 afteraging.

In one embodiment, the sag factor may be measured from a column of fluidhaving a is length of about 11 cm. In a further embodiment, column offluid may be housed in an aging cell with a headspace of about 2 cm. Fora vertical sag factor measurement, the top density may be measured about1 cm below the fluid surface, and the bottom density may be measuredabout 10 cm below the fluid surface (or about 1 cm from the bottom ofthe column). For an inclined sag factor measurement, the top density maybe measured about 1 cm directly below the fluid surface, or 1 cm belowthe fluid surface parallel to a sidewall of the aging cell. Similarly,the bottom density for an inclined cell may be measured 10 cm below thefluid surface parallel to a sidewall of the aging cell.

In related embodiments, sag stability is found to exist if the densityof the bottom 25% of drilling fluid increases by less than about 10% ofthe base fluid density, The percent change is over at least about 120hours of static aging and/or if the low shear rheological profile of thedrilling fluid changes by less than about ±25%, as measured by the dialreading at a rotation rate of 6 revolutions per minute (rpm) or less ona Farm Model 35 Viscometer.

Drilling fluids in deviated wellbores can exhibit sag in both static anddynamic situations. In this context, static is a totally quiescent fluidstate, such as when drilling has ceased; dynamic is any situation wherethe fluid is exposed to a shear stress, such as for example duringdrilling. As used hereinafter, the term “sag” shall be understood toinclude both static and dynamic sag unless specifically indicatedotherwise. Preferably the sag described here, especially in relation tocertain sag factors, is static, meaning that the sag is measured on adrilling mud composition in an aging cell not exposed to shear stress.

In one embodiment, the drilling mud composition has a sag factor in arange of 0.500-0.520, preferably 0.501-0.515, more preferably0.502-0.510, or about 0.503, at a vertical condition at a temperature of180-270° F., preferably 200-265° F., more preferably 220-260° F., orabout 250° F. and a pressure of 300-800 psi, preferably 400-700 psi,more preferably 450-650 psi, or about 500 psi. This sag factor may bemeasured after aging the drilling mud composition at the previouslydescribed temperature and pressure conditions for a time period of 6-96h, preferably 12-48 h, more preferably 18-36 h, or about 24 h. In someembodiments, the sag factor may be in a range of 0.520-0.530, forinstance, 0.521-0.523 or 0.525-0.528. In a further embodiment, with theabove conditions, the sag factor is 95% or less, preferably 92% or less,more preferably 90% or less, or 89% or less, or 85% or less of a sagfactor of a substantially similar drilling mud composition that does notcomprise the anti-sagging agent.

As described herein, the “inclined position” means that the aging cellor other vessel containing the drilling mud composition, is turned at anangle in a range of 30-60°, preferably 35-55°, more preferably 40-50°,or about 45° from the vertical. FIG. 2B shows an example of an agingcell at an inclined position; FIG. 2A shows a disassembled aging cellhaving parts in a vertical position.

In one embodiment, the drilling mud composition at an inclined positionhas a sag factor in a similar range (or most preferably, about 0.504),at similar temperature, pressure and aging conditions. In someembodiments, the sag factor may be in a range of 0.520-0.530, forinstance, 0.521-0.523 or 0.525-0.528. With these conditions and at theinclined position, the sag factor is 90% or less, 87% or less,preferably 85% or less, 83% or less, 80% or less of a sag factor of asubstantially similar drilling mud composition at a similar incline thatdoes not comprise the anti-sagging agent.

As used herein, the term “gel strength” refers to the shear stressmeasured at a low shear rate after a drilling fluid has set quiescentlyfor a set period of time. According to standard API procedures, the gelstrength is measured after setting for 10 seconds and 10 minutes,although measurements at longer time intervals can also be made such as,for example, 30 minutes or 16 hours.

In one embodiment, the drilling mud composition has a ten-second gelstrength of 14.0 to 20.0 lbf/100 ft², preferably 15.0 to 19.5 lbf/100ft², more preferably 17.0 to 19.0 lbf/100 ft², or about 18 lbf/100 ft²,and a ten-minute gel strength of 40.0 to 47.0 lbf/100 ft², preferably42.0 to 46.5 lbf/100 ft², more preferably 43.0 to 46.0 lbf/100 ft², orabout 45 lbf/100 ft². These gel strengths may he measured at atemperature of 60 to 150° F., preferably 70 to 100° F., more preferably75 to 90° F., or about 80° F.

As used herein, the term “yield point” refers to a parameter of theBingham plastic model, where yield point refers to the yield stressextrapolated to a shear rate of zero.

In one embodiment, the drilling mud composition has a yield point in arange of 35 to 47 lbf/100 ft², preferably 36 to 45 lbf/100 ft², morepreferably 37 to 43 lbf/100 ft², even more preferably 38 to 42 lbf/100ft², or about 40 lbf/100 ft², at a temperature of 60 to 150° F.,preferably 70 to 100° F., more preferably 75 to 90° F., or about 80° F.

In one embodiment, the drilling mud composition has a plastic viscosityin a range of 24 to 30 cp, preferably 24.5 to 28 cp, more preferably 25to 27 cp, or about 26 cp at a temperature of 60 to 150° F., preferably70 to 100° F., more preferably 75 to 90° F., or about 80° F.

In one embodiment, the drilling mud composition has a yield point toplastic viscosity ratio in a range of 1.15-1.80 lbf/(100 ft²·cp),preferably 1.30-1.70 lbf/(100 ft²·cp), more preferably 1.50-1.60lbf/(100 ft²·cp), or about 1.54 lbf/(100 ft²·cp), at a temperature of 60to 150° F., preferably 70 to 100° F., more preferably 75 to 90° F., orabout 80° F.

Preferably, the presence of the anti-sagging agent does notsignificantly affect filtration performance. In one embodiment, thedrilling mud composition has a filtrate volume that is within 20%,preferably with 18%, more preferably within 16% of the filtrate volumeof a substantially similar drilling mud composition that does not havethe anti-sagging agent and is subjected to the same filtrationconditions. In one embodiment, these filtration conditions may involve apressure in a range of 100-500 psi, preferably 150-450 psi, morepreferably 200-400 psi, or about 300 psi. A temperature during thefiltration may be in a range of 100-500 ° F., preferably 150-450° F.,even more preferably 200-300° F., or about 250° F. A median pore size ofthe permeable formation or of the filtration medium may he in a range of1-100 μm, preferably 10-80 μm, more preferably 30-70 μm. In oneembodiment, the filtrate volume may be measured after a filtration timeperiod in a range of 10-60 min, preferably 20-50 mm, more preferablyabout 30 min.

The drilling mud composition may be prepared by any suitable means knownin the art. In some embodiments, the drilling mud composition may beprepared at a well site or at an offsite location. Once prepared, thedrilling mud composition may be placed in a tank, bin, or othercontainer for storage and/or transport to the site to use. In otherembodiments, the drilling mud composition may be prepared on-site, forexample, using continuous mixing, on-the-fly mixing, or real-time mixingmethods. In certain embodiments, these methods of mixing may includemethods of combining two or more components wherein a flowing stream ofone element is continuously introduced into flowing stream of anothercomponent so that the streams are combined and mixed while continuing toflow as a single stream as part of the ongoing treatment. In someembodiments, the drilling mud composition may be made by a specificorder of adding and mixing components. For instance, the weighting agentmay be added last. Also, the anti-sagging agent may be added second tolast, or right before the weighting agent. In some embodiments, mixingmay proceed for a period of 1-30 minutes following the addition of eachcomponent, or similar components (for instance two fluid loss controlagents may be added simultaneously while mixing). In one embodiment, thedrilling mud composition may be formed by mixing the components in theorder shown in Table 2.

According to a second aspect, the present disclosure relates to a methodof drilling a subterranean geological formation using the drilling mudcomposition. This method involves drilling the subterranean geologicalformation to form a wellbore therein. The drilling mud composition ofthe first aspect is injected into the subterranean geological formationthrough the wellbore, often during the drilling. The anti-sagging agentprevents sagging of the weighting agent in the wellbore. In oneembodiment, the wellbore is a vertical wellbore, a horizontal wellbore,a multilateral wellbore, or an extended reach wellbore. A pumping systemmay be used to circulate drilling mud composition in the wellbore duringthe drilling.

The drilling mud composition be used during or in conjunction with otheroperations, such as pre-flush treatments, after-flush treatments,hydraulic fracturing treatments, sand control treatments (e.g., gravelpacking), “frac pack” treatments, acidizing treatments (e.g., matrixacidizing or fracture acidizing), wellbore clean-out treatments,cementing operations, workover treatments/fluids, and other operationswhere the dolling mud composition may be useful. In this sense, thedrilling mud composition may also be considered a completion or workoverfluid.

The examples below are intended to further illustrate protocols forpreparing, characterizing the drilling mud composition, and usesthereof, and are not intended to limit the scope of the claims.

EXAMPLE 1 Materials

A sample of commercial barite (obtained from a local supplier) with anaverage particle size of 30 microns was used in this study as aweighting material for water-based drilling fluid. The barite samplemainly contains 82 wt. % barium, 12.6 wt. % sulfur, and some otherimpurities. Table 1 lists the elemental composition of the barite samplethat was obtained using X-ray fluorescence technique (XRF). The particlesize distribution of barite sample is shown in FIG. 1 . Some additives(obtained from local supplier) were used to formulate the drillingfluid. Soda ash was used to maintain the level of calcium in the water.Bentonite and Xanthan polymer were used as viscosifiers to enhance therheological properties of the drilling fluid. Starch and PAC-R were usedto control fluid loss. Clay stabilization was maintained by addingpotassium chloride to the drilling fluid. Calcium carbonate was used asa bridging agent. See Caenn, R., et al., incorporated herein byreference in its entirety. Table 2 shows the drilling fluid formulationused in this study. The dimethylamino methyl ester-containing additivewas added in different concentrations to enhance the stability of thedrilling fluid and prevent solid settlement. Table 3 shows theproperties and the main components of the dimethylamino methylester-containing additive.

TABLE 1 The elemental composition of barite sample using XRF technique.Element wt. % mol % Si 1.9916 6.3483 S 12.6341 35.275 K 0.6331 1.4498 Ca0.1109 0.2478 Fe 1.3338 2.1383 Ni 0.0157 0.024 Cu 0.0354 0.0499 Sr0.5518 0.5638 Mo 0.017 0.0159 Ba 82.6171 53.8602 Ta 0.023 0.0114 Pb0.0366 0.0158

TABLE 2 Drilling fluid formulation. Field Units/ Mixing ComponentDescription Lab Units Time, min Function Water 0.7 bbl — Base Defoamer0.08 lb/g 1 Anti-foam agent Soda ash 0.5 lb/g 1 Maintain calcium levelXC-polymer 1.5 lb/g 20 Viscosifier Bentonite 4 lb/g 10 Viscosifier KOH0.5 lb/g 1 pH adjustment Starch 6 lb/g 10 Fluid loss control PAC-R 1lb/g 10 Fluid loss control KCl 20 lb/g 10 Clay stabilizer CaCO₃ 5 lb/g10 Bridging agent Barite 350 lb/g 10 Weighting material

TABLE 3 Properties and main components of the dimethylamino methylester-containing additive. Parameter Description Main components[Pentanoic acid, 5-(dimethylamino)-2- methyl-5-oxo-, methyl ester]58-59% [Lithium chloride] 1-2% Density 1.11 g/cc Dynamic viscosity 770mPa · s Water solubility Completely miscible Flash point >212° F.

EXAMPLE 2 Experimental—Fluid Preparation and Rheology Measurements

A barite-weighted drilling fluid, 15 ppg, was prepared using drillingfluid additives. Water was added with a ratio of 0.7 bbl (245 g inlaboratory units) and poured in the drilling fluid mixer container.Defoamer and soda ash were added to prevent the formation of foam and tomaintain the level of calcium in water, respectively. See Caenn, R., etal., incorporated herein by reference in its entirety. Then, otheradditives were added and mixed for a specific time, starting withviscosity control agents bentonite and xanthan polymer. The mixingstarted with low rotational speed then the speed was increased graduallyas the viscosity built up. Table 2 lists all drilling fluid additives,their amounts and functions, and the mixing time. Following the sameprocedure, several samples of drilling fluid were prepared by addingdifferent ratios of the new additive to the drilling fluid formulation(0.5, 1, 1.5, 2, and 3 vol. % of the total base fluid). The anti-saggingadditive was added right before adding the weighting material and mixedfor 5 minutes. After fluid preparation, fluid density was measured usingmud balance, and theological properties were measured at low and hightemperatures to study the effect of adding the new additive on drillingfluid rheology at different well conditions.

EXAMPLE 3 Experimental—Sag Tests

A sag test was conducted to study the effect of adding the new additiveon barite sag tendency. First, a drilling fluid sample was agitatedusing drilling fluid mixer. An aging cell was used to contain and keepthe fluid pressurized. A pressure of 500 psi was applied using nitrogento prevent fluid from evaporation and the aging cell was kept in theoven for 24 hours at specific temperature and static conditions. The sagtest was conducted at both vertical and inclined conditions (45degrees). After 24 hours, the cell was taken out and left to cool downand the pressure was released. Afterwards, two fluid samples were takenfrom the top and the bottom of the cell. The densities of the twosamples were measured and the sag factor was calculated using Equation1.

$\begin{matrix}{{{Sag}{Factor}} = \frac{\rho_{Bottom}}{\rho_{Bottom} + \rho_{Top}}} & (1)\end{matrix}$

where ρ_(Bottom)=Bottom density in ppg, and ρ_(Top)=top density in ppg.A fluid having a sag factor between 0.5 and 0.53 will have a good sagperformance, while a sag factor greater than 0.53 will result in a badsag performance where solid particle settlement is likely. SeeAlabdullatif et al., 2015; and Maxey, J., 2007. Rheological Analysis ofStatic and Dynamic Sag in Drilling Fluids. Paper presented at NordicRheology Conference. Stavanger, each incorporated herein by reference intheir entirety. FIGS. 2A and 2B shows sag test setup for vertical andinclined conditions. More specifically, FIG. 2A shows the disassembledcell, and FIG. 2B shows the cell assembled and inclined at a 45° angle.

EXAMPLE 4 Experimental—HPHT Filtration Experiments

Drilling fluid samples were agitated for 10 minutes, and then pouredinto the filtration cell to investigate the effect of the new additiveon filtration performance of the drilling fluid. The filtrationexperiments were performed at 250° F. and 300 psi, using a 50-micronceramic filter disc. The cell was heated up to 250° F. under a pressureof 300 psi which was applied using nitrogen gas. Then, the experimentswere started, and the filtrate volume was recorded with time. Theexperiments were run for 30 minutes. Afterwards, the filter cake wascharacterized by measuring its weight and thickness. Table 4 summarizesthe filtration experiment conditions.

TABLE 4 Filtration experiments conditions. Parameter Description Fluidvolume 350 mL Pressure 300 psi Temperature 250° F. Experiment duration30 min Ceramic filter disc 50-micron

EXAMPLE 5 Results and Discussion

When dial readings (shear stress) measured at room temperature wereplotted versus rotational speed (shear rate) for all drilling fluidsamples, it was found that adding the new additive to the drilling fluidshifted the consistency curve upward as the concentration of the newadditive increased. At the same time, the slope remained almostconstant, which indicates a significant increase in yield point(intercept with y-axis) without increasing the plastic viscosity (slope)(FIG. 3 ). FIG. 4 compares the rheological properties of all drillingfluid samples measured at room temperature. These properties are yieldpoint, plastic viscosity, and gel strength after 10 seconds and after 10minutes. A significant increase in yield point and gel strength wasobserved as the additive concentration increased, reflecting anenhancement on drilling fluid ability to suspend solid particles withoutsignificantly increasing drilling fluid plastic viscosity. Therefore,adding the new additive will require more pumping pressure on startupbecause of the increase in yield point, while it will not causeadditional frictional pressure losses during circulation.

Hole cleaning, barite sag, equivalent circulating density, surge andswab pressures, and other important drilling issues are impacteddirectly by yield-stress characteristics. See Power, D., and Zamora. M.,2003. Drilling Fluid Yield Stress: Measurement Techniques for ImprovedUnderstanding of Critical Drilling Fluid Parameters. PaperAADE-03-NTCE-35 presented at the AADE 2003 National TechnologyConference “Practical Solutions for Drilling Challenges.” Houston. April1-3, incorporated herein by reference in its entirety. The yield pointto plastic viscosity (YP/PV) ratio has been proposed as a tool toevaluate drilling fluid stability. Higher YP/PV ratios indicate morestabilization. See Chilingarian, G., Alp, E., Uslu, S., Gonzales, S.,and Ronald, J., 1983. Drilling Fluid Evaluation Using YieldPoint-Plastic Viscosity Correlation. Paper SPE 12469. July 27,incorporated herein by reference in its entirety. When YP/PV ratios werecalculated for all drilling fluid samples, it was found that as theconcentration of the new additive increased, the YP/PV ratio increased,indicating more stabilization to the drilling fluid (FIG. 5 ).Furthermore, drilling fluid rheology for the base fluid and with 0.5 and1 vol. % was measured at 250° F. and 2000 psi to evaluate theperformance of the new additive at high pressure and temperature. Allsamples showed a similar behavior to that at low temperature with lowervalues of yield point and plastic viscosity due to the high temperatureeffect (FIG. 6 and FIG. 7 ).

FIG. 8 shows the sag performance of the base drilling fluid undervertical and inclined conditions at 500 psi and at two differenttemperatures, 200 and 250° F. For inclined sag test, the degree ofinclination was set at 45° to simulate the worst scenario since thesettling process is accelerated when the inclination is above 30°. SeeSkalie, P., Backe, K. R., Lyornov, S. K., & Sveen, J. (1999). BariteSegregation in Inclined Boreholes. Journal of Canadian PetroleumTechnology, 38(13). p. 1-6, incorporated herein by reference in itsentirety. At 200° F., the base drilling fluid exhibited a god sagperformance in both cases, vertical and inclined, and the sag factor waswithin the safe range (0.5-0.53) with a value of 0.508 and 0.517,respectively. In contrast, the base fluid showed bad sag performance at250° F., and the sag factor was greater than 0.53 for both cases,therefore, barite sag is likely. Then, the new additive was added to thedrilling fluid formulation with different concentrations, 0.5-3 vol. %,and the sag test was performed at 250° F. for both vertical and inclinedconditions. As shown in FIG. 9 and FIG. 10 , adding the new additive tothe drilling fluid formulation showed a significant enhancement onstability and the sag factor was within the safe range (0.5-0.53) forall the drilling fluid samples; thus, barite sag is unlikely to occur atthose conditions. Since adding only 0.5 vol. % to the drilling fluidformulation prevented barite sag, 0.5 vol. % can be considered as anadvantageous concentration. Higher concentrations lead to an increasedyield point, which, to some extent, would have a negative impact becausemore pumping pressure would be required on startup. Besides, increasingthe concentration of additive more than needed will add more cost to thedrilling operation.

FIG. 11 compares the filtration performance of base fluid, 0.5 vol. %,and 1 vol. % drilling fluid samples. The filtration experiments wereperformed at 250° F. and 300 psi, and run for 30 minutes. It was foundthat adding the new additive to the drilling fluid formulation did notaffect the filtration performance significantly and all the drillingfluid samples had almost a similar filtration performance with adifference of around 1.5 mL in the total volume of fluid filtrate. Table5 summarizes the filtration experiment results.

TABLE 5 Filtration experiments summary. Parameter Base fluid 0.5 vol. %1 vol. % Filtrate volume, mL 9.6 11 10.7 Filter cake weight, g 29.134.94 29.77 Filter cake thickness, 0.14 0.168 0.14 inches

In this study, a barite-weighted drilling fluid formulation, with adensity of 15 ppg, was prepared by adding and mixing the drilling fluidadditives. Then, several fluid samples were prepared by adding differentratios of the new anti-sagging agent to the drilling formulation (0.5,1, 1.5, 2, and 3 vol. % of the total base fluid). Afterwards, the effectof adding anti sagging agent on the drilling fluid properties wasevaluated by measuring mud density, pH, theology, filtration, and sagtendency at low and high temperatures and both vertical and inclinedconditions.

1-5. (canceled)
 6. The method of claim 19, wherein barite in the bariteweighting agent is in the form of particles having a mean diameter in arange of from 20 to 70 μm.
 7. The method of claim 19, wherein the LiClis present in a range of from 1 to 2 vol. %. relative to the totalanti-sagging agent weight.
 8. The method of claim 19, wherein thedrilling mud composition has a density in a range of from 8.34 to 20ppg.
 9. The method of claim 19, wherein a volume concentration of themethyl 5-(dimethylamino)-2-methyl-5-oxopentanoate in the drilling mudcomposition is in a range of from 3.0 to 4.0 vol. %, relative to a totalvolume of the aqueous base fluid.
 10. The method of claim 19, whereinthe drilling mud composition further comprises a second fluid-losscontrol additive; a defoamer; a clay stabilizer; a bridging agent;antiscalant; a deflocculant; a lubricant; an anionic polyelectrolyte;and/or a surfactant.
 11. The method of claim 19, wherein the drillingmud composition has a sag factor in a range of from 0.500 to 0.520 at avertical condition at a temperature of in a range of from 180 to 270° F.and a pressure in a range of from 300 to 800 psi.
 12. The method ofclaim 19, wherein the drilling mud composition has a factor that is 90%or less of a sag factor of a substantially similar drilling mudcomposition that does not comprise the anti-sagging agent.
 13. Themethod of claim 19, wherein the drilling mud composition has a sagfactor in a range of from 0.500 to 0.520 at an inclined condition of ina range of from 30 to 60°, at a temperature of in a range of from 180 to270° F., and at a pressure in a range of from 300 to 800 psi.
 14. Themethod of claim 13, wherein the sag factor is 85% or less of a sagfactor of a substantially similar drilling mud composition that does notcomprise the anti-sagging agent.
 15. The method of claim 19, wherein thedrilling mud composition has a ten-second gel strength in a range offrom 14.0 to 20.0 lbf/100 ft², and a ten-minute gel strength in a rangeof from 40.0 to 47.0 lbf/100 ft², at a temperature in a range of from 60to 150° F.
 16. The method of claim 19, wherein the drilling mudcomposition has a yield point in a range of from 35 to 47 lbf/100 ft²,at a temperature in a range of from 60 to 150° F.
 17. The method ofclaim 19, which wherein the drilling mud composition has a plasticviscosity in a range of from 24 to 30 cp, at a temperature in a range offrom 60 to 150° F.
 18. The method of claim 19, wherein the drilling mudcomposition has a yield point to plastic viscosity ratio in a range offrom 1.15 to 1.80 lbf/(100 ft²·cp), at a temperature in a range of from60 to 150° F.
 19. A method of drilling a subterranean geologicalformation, comprising: drilling the subterranean geological formation toform a wellbore therein; injecting a drilling mud composition into thesubterranean geological formation through the wellbore, and circulatingthe drilling mud composition in the wellbore; wherein the drilling mudcomposition comprises, based on a total drilling mud composition weightwith weight percentages totaling to 100 wt. %: an aqueous base fluid ina range of from 35 to 60 wt. %; a viscosifier in a range of from 0.7 to1.0 wt. %, comprising bauxite, dolomite, limestone, calcite, vaterite,aragonite, magnesite, taconite, gypsum, quartz, marble, hematite,hectorite, bentonite, limonite, magnetite, andesite, garnet, basalt,dacite, nesosilicate, orthosilicate, sorosilicate, cyclosilicate,inosilicate, phyllosilicate, tectosilicate, kaolin, montmorillonitefullers earth, halloysite, XC-polymer and/or xanthan gum; a bariteweighting agent in a range of from 40 to 58 wt. %; a first fluid losscontrol additive in a range of from 1.0 to 1.2 wt. %, comprising starchguar gum, carboxymethyl cellulose, crospovidone, croscarmellose sodium,sodium starch glycolate polysaccharides, nolyanionic cellulose polymer,and/or acrylic polymer; and an anti-sagging agent in a range of from 0.1to 1.2 wt %, wherein the anti- sagging agent comprises LiCl and methylester 5-(dimethylamino)-2-methyl-5-oxopetanoate in a range of from 40 to70 wt. %, relative to total anti-sagging agent weight, and wherein ayield point/plastic viscosity ratio of the drilling mud composition isin a range of from 2.5 to 2.6, wherein the anti-sagging agent preventssagging of the weighting agent in the wellbore.
 20. The method of claim19, wherein the wellbore is a vertical wellbore, a horizontal wellbore,a multilateral wellbore, or an extended reach wellbore.